Outline: Produce I2, hold I2, produce I- with Na2S2O3
Why NaHCO3 is added: One of the main reasons of Iodometric titrations is the missing of Iodide which can happen for reasons ranging from air oxidation to vaporization/evaporation. That is because Iodide ion is very reactive. NaHCO3 reacts with iodine to form a harmless product NaI.
Why NH4SCN:
